Ion exchange resins global industry analysis, size. A 114 eductor with 80 psig supply pressure will transfer about 1 cu. The ionexchange capacity iec is one of the fundamental characteristics of ionselective membranes. Ion exchange chromatography iex separates proteins with differences in surface charge to give highresolution separation with high sample loading capacity. Rohm and haas1 available on the internet as a pdffile, which one can read and print but cant calculate. The separation occurs by reversible exchange of ions between the ions present in the solution and those present in the ion exchange resin. The separation is based on the reversible interaction between a charged protein and an oppositely charged chromatography resin. Calculate the capacity required to handle the tea content of the feed for the desired feed rate and.
The beads are typically porous, providing a large surface area on and inside them the trapping of. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally. This book focuses on the plateequilibrium theory of chromatography, which is less difficult theoretically than the masstransfer theory. This negative charge is usually expressed in milliequivalents per 100 grams meq100 g of soil. Move resin drums into position and fill with water 2. Resin description of process ion exchangers are synthetic resins organic polymers.
Chemical degradation of ion exchange resins may be caused by fouling the resin pores by precipitates e. If i have a cation exchange membrane and need to remove 2 gl of sodium, how much resin would i need. Total amount of chemical equivalents available for exchange per unit weight or. The calculator also shows some calculations that are needed for the sizing of an. Determination of the exchange capacity of a cation ion. For weak acid cation resin, operating capacity depends on several parameters, so there is no such simple estimate. The term equivalent is defined as one gram atomic weight of hydrogen or the amount of any other ion that will combine with or displace this amount of hydrogen.
And from the manual of the tester, the final absorbance is reached. Softener operation basic ion exchange process thumb rules of designing a softener step 1 to select resin quantity ltrs for a particular hardness ppm for a particular output m3 per regeneration per hour based on regeneration level 160 gmltr, ion exchange capacity 55, tds limit 1500 ppm refer table 1 resin quanitity load ppm as caco3 flow time ex. How to calculate the cation exchange resin capacity. With proper design and operation, ion exchange processes are capable of removing selected ions almost completely in some cases to a fraction of a part per million. While these products and services are focused on the power generation market, they are also used for petrochemicals, pharmaceuticals and industrial waters. Standard test method for column capacity of particulate mixed.
Ion exchange resins or zeolites have a limited number of ex available, and the total solidphase concentration, q o, is termed the ion exchange capacity. For cation exchange resins, it is usually between 200 to 500meq per 100 gms. Dowex cation and anion exchange resins, used separately or in. Ion exchange in analytical chemistry provides a broad survey of the important role that ion exchange can and should play in chemical analysis. Ion exchange resins are polymers that act as ion exchange mediums. The high molecular weight polymer is normally in the form of small, round spheres called beads. But this will not give me the correct mass since the resin is a polymer with that functional group attached. Application guide water softening basics ion exchange resin.
The resin beads can then be regenerated by a high concentration 10% brine of salt or other regenerant chemical to restore the resins capacity, enabling the system to be used over and over for many years. Resin for industrial demineralization, water filtration. Using the average breakthrough capacity from the experiments a design was made for four ion exchange vessels with each a capacity of 120m3h, a bed height of 2m, and surface loading of 99mh, and empty bed contact time ebct of 1. Standard test method for column capacity of particulate. Calculate the bed depth and shell diameter for the. Determination of the ionexchange capacity of anion. Once capacity is calculated in gl or ft 3, multiply that number by the number of liters or cubic feet of resin in the system to get system capacity. How to calculate resin capacity for softener softening. It is an insoluble matrix or support structure normally in the form of small 0. It is assumed that the breakthrough capacity remains the same. The correct performance from any ion exchange resin bed unit can only be achieved if the resin is loaded, commissioned and operated correctly. The unit of mole should be avoided altogether in ion exchange, as it does not take valence into account and brings only confusion.
An ion exchange system consists of a bed of resin beads with the ability to pick up hardness or other elements by ion exchange. Determine the separation factor for an ion with respect to the other ions in the water. An ionexchange resin or ionexchange polymer is a resin or polymer that acts as a medium for ion exchange. Determine the equilibrium composition of the resin, thus calculating how much of the exchange capacity is used by the different ions. Various exchange active groups, at which ions accumulate, are built into the exchangers. To apply this equation it is necessary to perform a laboratory column test or pilot. At what point is the cost of new ion exchange resin lower than the cost of excess regenerant chemicals.
In the exchange process, the ions of the solution to be treated are exchanged with accumulated. October 14, 2015 the dow chemical company page 3 of 7 product uses2,7,8,6 dow ion exchange resins are used in a. How to calculate resin capacity for softener softening plant. Determination of the ionexchange capacity of anionselective. Overview ion exchange resin is primarily used in water and waste water treatment. Total capacity will be the same value regardless of the challenge ions because it represents the total of all exchange sites on the resin. Ion exchange usually describes a processes of purification of aqueous solutions using solid polymeric ion exchange resin.
In ion exchange processes, we define not only the quantitative capacity of the resin as total capacity, but the qualitative capacity as well as. Transfer1gramofcationexchangeresintoa150or250mlbeaker. Connect and secure the discharge hose to the exchange tank. Metsorb utilizes a patented titanium compound to adsorb both forms of arsenic as well as a wide range of contaminants in water. This is the number of sites where exchange actually takes place during one cycle. Total capacities of new resins are measured for quality control. Ion exchange products graver technologies designs, processes and manufactures a wide range of ion exchange products. Various exchangeactive groups, at which ions accumulate, are built into the exchangers. A highperformance liquid chromatographic method using a borateformate buffer system and an aminex a27 ionexchange resin has been developed for the separation of heptose nucleotides from. The resin has a standard exchange capacity of 1,4 eql and a density of 0,7 kgl.
Ion exchange chromatography ge healthcare life sciences. Information on properties of ionexchange resins is supplied to users in two. Example calculation to illustrate the equations used by the calculator. Very highly crosslinked, high capacity, hydrogen form gel strong acid cation resin intended for use in radwaste and other single use applications where the highest possible capacity is needed. In the literature 1 you can find the following values for selectivity coefficients and separation factors table 6. Simply start by selecting a resin and entering a few key data from your plant. The ion exchange capacity of a resin is a measurement of the ion amount that it is able. Astm d2187 17 standard test methods and practices for.
The ion exchange capacity is expressed as eql equivalents per litre of resin. Information on the ion exchange resin on the internet figure 1 shows a part of technical process bulletin of ion exchange resin amberjet 1200 na produced by rohm and haas1 available on the internet as a pdf file, which one can read and print but cant calculate by it. The ion exchange capacity iec is one of the fundamental characteristics of ion selective membranes. The operating capacity for the resin will be specific to the test conditions, flow, challenge level, degree of regeneration, etc. Each unit with a capacity of 120m3hour average breakthrough capacity of 2. So far, the most widely used technique for iec determination is titration.
Since a cation exchanger must remain electrically neutral during the exchange reaction, all of the exchange. However, this method is very sensitive to experimental conditions, especially when anionselective membranes are treated. More precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Since dozens of factors can impact the productivity of the system, the cadix system design software program from dow offers precise design recommendations to optimize system performance. If our challenge water is 16 gpg, we calculate the system capacity as 140,00016 8,750 gallons. The raw water has total hardness of 100 mgl as caco 3. In this case, 100m3 to be softened at 400 ppm of feed hardness to 5 ppm. In the exchange process, the ions of the solution to be treated are exchanged with accumulated ions with the same electrical charge on the resin. The charged molecules in the sample are separated by the electrostatic forces of attraction when passed through the ionic resin at particular ph and temperature. Ion exchange resins are functionalized polymer microbeads, which are usually yellow or white in color.
All cations and anions will be exchanged, and in this case the net result is a complete disappearance of the ionic contaminants. Ion exchange selectivity the selectivity coefficientk b and the separation factora b are directly proportional to the preference of a given ion exchange resin toward different types of ions for the same concentration of different ions the relative preference of an ion exchanger depends primarily on two factors, i. The typical operating capacity of a weak base anion exchange resin is 70 to 90 % of the total capacity. Resin capacity will vary depending upon the salt dose per cubic foot of resin and can be approximated from the following table. Mpw carries various resin products for industrial demineralization in water filtration systems. Let our resin replacement calculator help you determine this point for your plant. Live calculations, functions and calculation procedures on. Harsh abstract many students in introductory soil science and soil chemistry courses have difficulty understanding the chemical concepts that are associated with expressing cation exchange capacity in either equivalent units or the. The operating capacity is always smaller than the total capacity. To do this, you need a cation exchange resin in the h form and an anion exchange resin in the oh form. Steps to design an ion exchange resin system accurate system design is critical to getting the most from a water treatment system. We want to eliminate anions from the water so we have to use an anionic resin. The primary applications are for trace contaminant removal in high purity.
Before to calculate the capacity of the water softener softening plant, to choose how much water to be softened. Not only are the accumulated solids removed, but ion exchange resin can go with it, resulting in a reduced capacity, due to resin inventory. An ion exchange process is to be used to soften water at the rate of 500 gpm. This file can be also found on the site of developing company or on the calculation site of. Ion exchange chromatography resins can be used at high flow. These in turn influence the numerical values obtained in exchange capacity determinations, in density measurements, and in the size of the particles. The resin exchange capacity is mention into the products supplier data sheet. Figure 1 shows a part of technical process bulletin of ionexchange resin amberjet 1200 na produced by rohm and haas1 available on the internet as a pdf file, which one can read and print but cant calculate by it. They are insoluble in water, crosslinked, and chemically inert. Exchange resin introduction ion exchange is a process in which ions attached to a high molecular weight polymer are exchanged for other ions in solution. The exchange capacity, in milliequivalentsgram of resin, is calculated using the formula. How to calculate ion exchange capacity theoritically.
Ion exchange resins are used to demineralize water and to. Aside from its use to purify drinking water, the technique is widely applied for purification and. Ion exchange processes table 1 types of ion exchange materials capacity exchangers kgrft3 cation inorganic zeolites natural. The following information gives guidelines for the loading and commissioning of different types of ion exchange plants. Calculate the amount of salt required for regeneration. Practical considerations of ion exchange resins in the. The ion exchange resin manufacturers publish performance data allowing users to calculate the operating capacity of their resins under the most. The resin has an exchange capacity of 320 kilograins of caco 3 per ft when regenerated at the 3rate of 15 ib of salt per ft. A synthetic zeolite resin will be packed in shells with diameter of 5 ft.
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